Friday, October 18, 2019
HRM Innovation and Change Essay Example | Topics and Well Written Essays - 500 words - 2
HRM Innovation and Change - Essay Example The chapter elaborates that the traditional role of managers were confined to the well defined parameters of organizationââ¬â¢s goals and management guidelines. Leadership, on the other hand, basically refers to people who have the capacity to bring about changes in other people. Indeed, leaders create visions and goals whereas the managers and administrators work towards achieving them. Hence, in the contemporary environment competitive business, managerial leadership has become the need of the hour. The examples of the dynamic leadership of Leahy of Tesco and Oââ¬â¢Leary of Ryanair illustrates that to develop effectiveness in strategic change, flexible approach to managerial leadership that is more labor friendly needs to be adopted. It should also believe in developing joint goals and objectives that are mutually beneficial, thus fostering mutual beliefs and better understanding of each others value system. Project can broadly be defined as a specific time bound work with specific objectives and goals; budget; and resources. I believe that the successful completion of project therefore, requires teamwork that is defined by shared leadership. Leadership helps to promote smooth functioning of the various processes within the parameters of project goals. The cut throat business environment demands dynamic leadership who strives to create value based mission and inculcates confidence amongst the various stakeholders. Indeed, the project management helps provide the tools to achieve project goals through well planned strategy. At the same time, the managerial leadership would not only facilitate an intangible stability among the team members but also provide impetus for improved performance that result in efficient and time bound completion of the
Thursday, October 17, 2019
What Happened to Coca Cola Companys challenges of Coca Cola Case Study
What Happened to Coca Cola Companys challenges of Coca Cola - Case Study Example Many challenges and companyââ¬â¢s fiasco are caused by intolerant policy of the company directed on racial, gender or religious discrimination against its employees. On the example of Coca Cola failures on the basis of racial discrimination issues, it is clearly seen that careful and equitable attitude to all employees is a guarantee of the companyââ¬â¢s success and a protection against companyââ¬â¢s failures. What about diversity, Coke? A famous lawsuit in 1999, which accused the company of racial discrimination against black employees, even after a challenging resolution, resulted in further racial persecutions in the company (What Happened to Coca Cola? p. 264). It would be better for Coca Cola to prevent incidents of racial discrimination at work, because the major part of potential clients is ethnic minorities. Accoring to Joe Solmonese, President, Human Rights Campaign, ââ¬Å"The Coca-Cola Company is a model employer for diversity and inclusion within its own work for ce and as a member of the larger business community. Its leadership on lesbian, gay, bisexual and transgender equality in the workplace is not only reflected in its long-standing achievement of 100 percent on the Corporate Equality Index, but in its principled support of anti-discrimination legislation that would protect every worker in the United States from being judged on the basis of their sexual orientation or gender identityâ⬠(Creating an inclusive workplace). ... In reality, it was evident that Coca Cola appreciated ethnic minorities as their customers and not employees. The Task Force underlined that it was relevant to evaluate career opportunities for white employees with career opportunities for black employees. In spite of the fact that the company hired a third of employees from ethnic minorities, top positions of the company were taken by white employees. It would be relevant to promote to the higher rank positions black employees and in such a way, other employees would realize that they have a real chance to occupy a better position in the company. That is why the majority of plaintiffs did not miss their chance and joined other plaintiffs in the famous lawsuit of 1999. People felt like having a real opportunity to renovate just and tolerant policy at workplace. Unfortunately, their hard struggle did not lead to a complete success. The issues of diversity are still believed to be invented by managers in the company. There is no proof or evidence that there are many examples of career promotion among black employees in the Coca Cola Company. Consequently, the fact that black employees felt indignant and cooperated in the name of equitable attitude at work may be justified. In accordance with Parker, steps made by black employees (plaintiffs) could be explained with regards to Parkerââ¬â¢s triangle ââ¬Å"The Emotional Connection of Distinguishing Differences and conflictâ⬠. He explains that emotions of black employees were hurt and they had no other way out, but to join to other claimants and to fight against racial discrimination in the company. Conclusion Thus, we can claim that Coca Cola made fake attempts to reach diversity in the company. In the majority of cases managers were just saying some words describing
Motivation Speech or Presentation Example | Topics and Well Written Essays - 500 words
Motivation - Speech or Presentation Example This is useful to the organization because it will manage to achieve its own objectives, satisfying its customers and the various stakeholders of an organization. Take for example a cashier serving customers in a retailing organization; a cashier who is well motivated will be (Higgins, 2012); On this basis, the advantages of motivating the employees of an organization will result to the production of high quality work (Karabenick and Urdan, 2010). It is always the role of a manager to motivate his own work force. There are a number of ways and methods of motivating the workforce of an organization. These methods include, It is important to denote that these activities fall under a motivational theory. There are a number of motivational theories developed by scholars of management and psychology. One such theory is the expectancy theory. This is a theory developed by Victor Vroom, and it gives a proposal that people will behave in a certain manner, because of a reward that is attached to the action under consideration (Higgins, 2012). For example, an employee in a manufacturing organization will decide work double shifts in case of shortages of work force, and in return, the employee will expect to get some compensation and praise from the management. Another theory is the equity theory developed by John Adams in 1963. This theory denotes that employees of an organization will be motivated if they are treated equally. For example, if employees of an organization perform the same job, i.e. they are both accountant, then the management should pay them an equal salary (Karabenick and Urdan, 2010). Failure for an organization to treat its employees equally could result to a de-motivated work force. Another theory is the hierarchy of needs theory by Abraham Maslow (Higgins, 2012). This theory denotes that the employees of an organization have several needs, and they are hierarchical in
Wednesday, October 16, 2019
Ethics The Element of Moral Philosophy by Rachels, Meditations ( Essay
Ethics The Element of Moral Philosophy by Rachels, Meditations ( Marcus Aurellius), A man For All Seasons (Bolt) - Essay Example Additionally, the origin of morals and moral behavior is relatively unknown; as is what components a person must consider when deciding whether his or her actions would be considered moral. Unlike many consequentialists, Kant asserts deontological, or "Duty Based" morals. Essentially, morals come directly from the will of the person taking action; that person will do the right thing simply because it is the right thing to do. This approach to ethics is the easiest to teach, the first people learn, and the most cut-and-dry approach to ethics and moral influence available. The Kantian approach to morality relies heavily on universal acceptance and implementation of "laws" such as whether or not a person should lie, steal, or murder. Clearly, to lie, steal, or murder is wrong; therefore a moral person will never lie, will never steal, and will never murder another person. The idea of "Universal Acceptance and Application of Laws" is known as the Categorical Imperative. Kant describes this Categorical Imperative as a personal choice: act in a manner that you would like to see become a universal law. This is somewhat akin to the "Golden Rule" - in a sense. In essence, this ideal asserts that while a person is deciding whether or not to do something (such as lie) to first consider whether or not that action should be done to him. To work with the example of lying: if a person does not believe that lying should be a universally accepted practice, then that person - through logic and reasoning - should not lie under any circumstances. Deontological ethics are rarely concerned with the outcome of an action - only the action itself is measured in terms of moral evaluation. Therefore, the Kantian approach to ethics is largely impartial and more objective than other views of moral behavior. As stated by Kant, there are no exceptions within this approach to ethics and morals. If it is wrong to lie, then at no time should a person lie. No matter the outcome of a situation, deontological ethics define a person as morally right if that person did not lie. For example, people seeking employment often have to write up resumes and/or fill out job applications. Some jobs require a certain amount of experience or training within the profession - or possible a particular personality - to consider an interviewee for employment. While filling out the application, duty-based ethics would require that a person be forthright with his or her information and personality traits - even if doing so may cost him or her employment. If the result of being honest results in the loss or foreclosure of the home, the act of being honest about his or her experiences on the job application is still measured as morally correct. The Kantian approach to ethics and morals is not without its flaws; some concepts simply cannot be categorized as "universal" and other should not. For example, if one persons morals infringes upon the rights or morals of another person. The use of contraceptives can be used as an example of this. If people were to universally stop the use of contraceptives, the world would become much more populated than it already is. Teen pregnancy would being to increase, and subsequently the number of abortions and adoptions would increase proportionally. However, if everyone universally began using
Motivation Speech or Presentation Example | Topics and Well Written Essays - 500 words
Motivation - Speech or Presentation Example This is useful to the organization because it will manage to achieve its own objectives, satisfying its customers and the various stakeholders of an organization. Take for example a cashier serving customers in a retailing organization; a cashier who is well motivated will be (Higgins, 2012); On this basis, the advantages of motivating the employees of an organization will result to the production of high quality work (Karabenick and Urdan, 2010). It is always the role of a manager to motivate his own work force. There are a number of ways and methods of motivating the workforce of an organization. These methods include, It is important to denote that these activities fall under a motivational theory. There are a number of motivational theories developed by scholars of management and psychology. One such theory is the expectancy theory. This is a theory developed by Victor Vroom, and it gives a proposal that people will behave in a certain manner, because of a reward that is attached to the action under consideration (Higgins, 2012). For example, an employee in a manufacturing organization will decide work double shifts in case of shortages of work force, and in return, the employee will expect to get some compensation and praise from the management. Another theory is the equity theory developed by John Adams in 1963. This theory denotes that employees of an organization will be motivated if they are treated equally. For example, if employees of an organization perform the same job, i.e. they are both accountant, then the management should pay them an equal salary (Karabenick and Urdan, 2010). Failure for an organization to treat its employees equally could result to a de-motivated work force. Another theory is the hierarchy of needs theory by Abraham Maslow (Higgins, 2012). This theory denotes that the employees of an organization have several needs, and they are hierarchical in
Tuesday, October 15, 2019
Social Class Differences in Education Essay Example for Free
Social Class Differences in Education Essay The claim that social class differences in education through school factors is supported by the interactionists such as George H. Mead. They believe that labelling theory encourages the educational achievement in different social classes. The labelling theory is when the teacher identifies major characteristics of a student. Research shows that teachers are more likely to label middle class children as bright and well behaved but working class children as naughty and disruptive. Following the label being attached on the child is self fulfilling prophecy, this is when the child will respond and act according to the label being placed on them, so a middle class student will act well behaved and complete the work that is set whereas the working class student will disrupt and not complete the work set and therefore not do well in exams. This shows that labelling working and middle class students affects the educational achievements because of their social class. However George H.Ã Mead can be criticised by material/cultural deprivation. Material deprivation is when the child doesnt have the right equipment for school e. g. books, and cultural deprivation is when the children havent been given the correct norms and values for attitudes to education. This shows that it is not only school factors that affect the differences in education achievement but it is also home factors. Marxists such as Willis would argue that counter school subcultures are the reason why different social class are achieving and underachieving. He claims that working class boys reject the whole idea of school and see school as a place of laughs and a matter of amusement because they do not have the correct norms and values, the see schools as boring so the disrupt lessons and breaking school rules. This behaviour will lead to low grades and therefore low pay jobs in the future. This shows that difference in social class results to different educational achievement. It can be argued that the working class children do not think about the uture also known as cultural capital, working class children only see how they should enjoy themselves in the present time and not what the rewards of education will be later on in life, this could be due to the rise in lone parent mothers and boys do not see a role model father and therefore do not value education, this shows that it is not only school factors that affect the educational achievement but it is home factors as well. Gillborn and Youdell argued that examination sets are split into two tiers, foundation and higher. Pupils that are entered for the foundation paper can not achieve higher than a C, pupils who are entered in for the higher paper are able to achieve A*. middle class students are more likely to be entered in the higher paper and working class are placed in the foundation. This shows that educational achievement is because of school factors and that working class pupils are not given a fair opportunity to education. However Sugarman would argue that educational achievement is not only because of school factors it is also home factors this could be due to class subcultures. He describes working class pupils as fatalistic and that they accept their position rather than trying to improve this. Pupils are not given the motivation for parents to try and improve. Evidence shows that there are may reasons why difference in social class leads to different educational achievements so therefore evidence remains inconclusive.
Monday, October 14, 2019
Extraction of Essential Oils Using Steam Distillation
Extraction of Essential Oils Using Steam Distillation Acknowledging about the importance of plants and its medicinal value research work is being done on the plant material. There are also over 200 references to aromatics, incense and ointments in the Old and New Testaments; Frankincense, Myrrh, Galbanum, Cinnamon, Cassia, Rosemary, Hyssop and Spikenard are noted for being used for anointing rituals and healing of the sick. Research has confirmed centuries of practical use of essential oils, and we now know that the fragrant pharmacy contains compounds with an extremely broad range of biochemical effects. The oils normally bear the name of the plant species from which they are derived. Essential oils are so termed as they are believed to represent the very essence of odor and flavor. The recovery of essential oil (the value added product) from the raw botanical starting material is very important since the quality of the oil is greatly influenced during this step. There are a variety of methods for obtaining volatile oils from plants. S team distillation method is found to be one of the promising techniques for the extraction of essential oil from plants as reputable distiller will preserve the original qualities of the plant and is being done in Clevenger apparatus. Analysis of Essential oil is done Gas Chromatography which gives us some indications of the quality and authenticity of the oil. CHAPTER 1: INTRODUCTION Essential oils contain highly volatile substances that are isolated by a physical method or process from plants of a single botanical species. The oils normally bear the name of the plant species from which they are derived. Essential oils are so termed as they are believed to represent the very essence of odor and flavor. Essential oil plants and culinary herbs include a broad range of plant species that are used for their aromatic value as flavorings in foods and beverages and as fragrances in pharmaceutical and industrial products. Essential oils derive from aromatic plants of many genera distributed worldwide. Oils are used in the embalming process, in medicine and in purification rituals. There are also over 200 references to aromatics, incense and ointments in the Old and New Testaments. Research has confirmed centuries of practical use of Essential Oils, and we now know that the fragrant pharmacy contains compounds with an extremely broad range of biochemical effects. There are about three hundred essential oils in general use today by professional practitioners. Continual bombardment of viral, bacterial, parasitic and fungal contamination occurs in our body. Essential oils are a great benefit to help protect our bodies and homes from this onslaught of pathogens. Immune system needs support and these essential oils can give the required endorsement. [1] Steam distillation is used in the extraction of Essential Oil from the plant material. It is a special type of distillation or a separation process for temperature sensitive materials like oils, resins, hydrocarbons, etc. which are insoluble in water and may decompose at their boiling point. The fundamental nature of steam distillation is that it enables a compound or mixture of compounds to be distilled at a temperature substantially below that of the boiling point(s) of the individual constituent(s). Essential Oil contains components with boiling points up to 200à °C or higher temperatures. In the presence of steam or boiling water, however, these substances are volatilized at a temperature close to 100à °C, at atmospheric pressure. [2] Analysis of Essential Oil is done by using Gas Chromatography with Mass Spectrometer. The qualitative and quantitative analysis is done to know the constituents in the oil and the percentage of components present in the oil respectively, by doing so we can know the purity of that particular oil. [3] CHAPTER 2:à LITERATURE REVIEW It is estimated that there are 250,000 to 500,000 species of plants on Earth. A relatively small percentage (1 to 10%) of these is used as foods by both humans and other animal species. It is possible that even more are used for medicinal purposes (Moerman, D. E. 1996). Moerman (1996) reported that while 625 species of plants have been used by various Native American groups as food, 2,564 have found use as drugs. According to his calculations, this leaves approximately 18,000 species of plants which were used for neither food nor drugs. [4] Plant oils and extracts have been used for a wide variety of purposes for many thousands of years (Jones 1996). These purposes vary from the use of rosewood and cedar wood in perfumery, to flavoring drinks with lime, fennel or juniper berry oil, and the application of lemongrass oil for the preservation of stored food crops. In particular, the antimicrobial activity of plant oils and extracts has formed the basis of many applications, including raw and processed food preservation, pharmaceuticals, alternative medicine and natural therapies. Since ancient times, herbs and their essential oils have been known for their varying degrees of antimicrobial activity. More recently, medicinal plant extracts were developed and proposed for use in food as natural antimicrobials. 2.1 DEFINITION: An essential oil is a concentrated, hydrophobic liquid containing volatile aroma compounds from plants. Essential oils are also known as volatile, ethereal oils or aetherolea, or simply as the oil of the plant from which they were extracted, such as oil of clove. Oil is essential in the sense that it carries a distinctive scent, or essence, of the plant. [5] Essential oils are frequently referred to as the life force of plants. These essential oils are extracted from flowers, leaves, stems, roots, seeds, bark, and fruit rinds. The amount of essential oils found in these plants can be anywhere from 0.01 percent to 10 percent of the total. These oils have potent antimicrobial factors, having wide range of therapeutic constituents. These oils are often used for their flavor and their therapeutic or odoriferous properties, in a wide selection of products such as foods, medicine, and cosmetics. Only pure oils contain a full spectrum of compounds that cheap imitations simply cannot duplicate. [5] 2.2 CHEMICAL CONSTITUENTS OF ESSENTIAL OILS: An Essential Oil contains more than 200 chemical components, but some are many times more complex. Essential oils consist of chemical compounds which have hydrogen, carbon and oxygen as their building blocks. They can be essentially classified into two groups: Volatile fraction: Essential oil constituting of 90-95% of the oil in weight, containing the monoterpene and sesquiterpene hydrocarbons, as well as their oxygenated derivatives along with aliphatic aldehydes, alcohols, and esters. Nonvolatile residue: This comprises 1-10% of the oil, containing hydrocarbons, fatty acids, sterols, carotenoids, waxes, and flavonoids. However the properties of these components can change. For example, the components from the oils extracted from plants can change according to how, when and where these plants are grown and harvested. [6] The constituents can be again subdivided into 2 groups, such as the hydrocarbons which are made up of mostly terpenes and the oxygenated compounds which are mainly alcohols, aldehydes, esters, ketones, phenols and oxides. Some of the common components are listed below along with their properties. Alcohols: Alcohols are generally considered safe and have a very low or totally absent toxic reaction in the body or on the skin and so can be used on children. They are extremely useful due to their antiviral, antibacterial and antiseptic properties. Alcohols are present either as a free compound or combined with a terpene or ester and are found in ylang -ylang and lavender as linalool, geraniol in geranium and palmarosa and citronellol found in rose, lemon and eucalyptus. Other alcohols include menthol, nerol and benzyl alcohol. Alderhydes: Alderhydes are found in lemon-scented oils such as Melissa, lemon verbena, citronella etc. and include citral, citronellal and neral. They generally have sedative qualities with specific antiseptic properties. Other known alderhydes include benzaldehyde, cinnamic alderhyde and perillaldehyde. Essential oils containing alderhydes are helpful in treating inflammation, Candida and viral infections. [6] Hydrocarbon: Building blocks of Essential Oil are hydrogen and carbon. Basic Hydrocarbon found in plants is isoprene having the following structure. (Isoprene) Terpenes: These components generally have names ending with ene. Some of them are limonene, pinene, piperene, camphene etc. These components act as an antibacterial, antiviral, anti-inflammatory, antiseptic, antiviral and bactericidal. These are further categorized into monoterpene, sesquiterpene and diterpenes. When two of the isoprene units are joined head to tail, the result is a monoterpene, when three are joined, its a sesquiterpene and similarly four linked isoprene units are diterpenes. Monoterpene [C10H16]: Monoterpene are naturally occurring compounds, the majority being unsaturated hydrocarbons (C10).But some of their oxygenated derivatives such as alcohols, Ketones, and carboxylic acids known as monoterpenoids. (Limonene) (Menthol) Two isoprene units are present in these branched-chain C10 hydrocarbons and are widely distributed in nature with more than 400 naturally occurring monoterpenes. Moreover, besides being linear derivatives (Geraniol, Citronellol), the monoterpenes can be cyclic molecules (Menthol Monocyclic; Camphor bicyclic; Pinenes (ÃŽà ± and ÃŽà ²) Pine genera as well. Thujone (a monoterpene) is the toxic agent found in Artemisia absinthium (wormwood) from which the liqueur absinthe, is made. Borneol and camphor are two common monoterpenes. Borneol, derived from pine oil is used as a disinfectant and deodorant. Camphor is used as a counterirritant, anesthetic, expectorant, and antipruritic, among many other uses. Sesquiterpene: Sesquiterpenes are biogenetically derived from farensyl pyrophosphate and in structure may be linear, monocyclic or bicyclic. They constitute a very large group of secondary metabolites, some having been shown to be stress compounds formed as a result of disease or injury. These are having properties like anti-inflammatory, anti-septic, analgesic and anti-allergic. Sesquiterpene Lactones: These are available as farnesene in chamomile and lavender. They not only have proved to be of interest from chemical and chemotaxonomic point of view, but also possess many antitumor, anti-leukemia, cytotoxic and antimicrobial activities. Chemically the compounds can be classified according to their carboxylic skeletons; thus, guaianolides, pseudoguaianolides, eudesmanolides, eremophilanolides, xanthanolides, etc. can be derived from the germacranolides. Structural features of all these compounds are associated with much of the biological activity. For example beta-caryophyllene in basil and black pepper Diterpenes: Isoprene has been an integral part in most of the components as there are four isoprene units in Diterpenes. By Stem Distillation method we cannot detect Diterpenes as this molecule is too heavy to allow for evaporation, so it is rarely found in distilled Essential Oils. Diterpenes occur in all plant families and consist of compounds having a C20 skeleton. There are about 2500 known Diterpenes that belong to 20 major structural types. Derivatives of Diterpenes are plant hormones Gibberellins and phytol occurring as a side chain on chlorophyll. The biosynthesis occurs in plastids and interestingly mixtures of monoterpenes and diterpenes are the major constituents of plant resins. In a similar manner to monoterpenes, Diterpenes arise from metabolism of geranyl geranyl pyrophosphate (GGPP). Therapeutically Diterpenes have limited importance and are used in certain sedatives (coughs) as well as in antispasmodics and anxiolytics. Alcohols: Naturally Alcohols exist either as a free compound or combined with a terpenes or ester. When terpenes are attached to an oxygen atom, and hydrogen atom, the result is an alcohol. When the terpene is monoterpene, the resulting alcohol is called a monoterpenol. Alcohols are not and are suitable to body or skin. Therefore, they are considered safe to use. Some of these properties are anti-septic, anti-viral, bactericidal and germicidal. Some of the examples are linalool found in ylang-ylang and lavender, geraniol in geranium and rose and nerol in neroli. Aldehydes: Aldehyde containing Essential Oils are effective in treating candida and other fungal infections. Some of these properties are anti-fungal, anti-inflammatory, anti-septic, anti-viral, bactericidal, disinfectant, and sedative. Aldehydes are present as citral in lemon, Citronellal in lemongrass, lemon balm and citrus eucalyptus. Acids: Generally Organic acids are found in very small quantities in their free state within Essential Oils. Plant acids act as components or buffer systems to control acidity. These also act anti-inflammatory. Examples are cinnamic and benzoic acid in benzoin, Citric and lactic. Esters: Esters are formed through the reaction of alcohols with acids. Essential oils containing esters are used for their soothing, balancing effects. Because of the presence of alcohol, they are effective antimicrobial agents. Medicinally, esters are characterized as antifungal and sedative, with a balancing action on the nervous system. They generally are free from precautions with the exception of methyl salicylate found in birch and wintergreen which is toxic within the system. Examples are linlyl acetate in bergamot and lavender and Geranyl formate in geranium. Ketones: Ketones found in plants are used for upper respiratory complaints. They assist the flow of mucus and ease congestion. Essential oils containing ketones are beneficial for promoting wound healing and encouraging the formation of scar tissue. Ketones are (not always) very toxic. The most toxic ketone is Thujone found in mugwort, sage, tansy, thuja and wormwood oils. Other toxic ketones found in essential oils are pulegone in pennyroyal, and pinocamphone in hyssops. Some non-toxic ketones are jasmone in jasmine oil, fenchone in fennel oil, carvone in spearmint and dill oil and menthone in peppermint oil. Lactones: Lactones are known to be particularly effective for their anti-inflammatory action, possibly by their role in the reduction of prostaglandin synthesis and expectorant actions. Lactones have an even stronger expectorant action than ketones. [Previous thesis] 2.3 ADVANTAGES OF ESSENTIAL OIL: AROMATHERAPHY: Aromatherapy is a form of alternative medicine that uses volatile plant materials, known as essential oils, and other aromatic compounds for the purpose of altering a persons mood, cognitive function or health. Science has discovered that our sense of smell plays a significant role in our overall health. Since ancient times Essential Oils have been used in medicine because of their medicinal properties, for example some oils have antiseptic properties. In addition, many have an uplifting effect on the mind, though different essential oils have different properties. Working of Essential Oil in Aromatherapy: when Essential Oil is inhaled it goes directly from olfactory system to limbic system of the brain. Brain responds to the particular scent affecting our emotions and chemical balance. Essential Oils also absorbed by the skin and carried throughout the body via the circulatory system to reach all internal organs. We can be benefited by choosing carefully the desired and suitable oils which can promote overall health. Benefits depend upon the unique nature of each persons response to an aromatic stimulus. [1] Importance of Essential Oil in pharmaceutics: Essential Oils have versatile applications in pharmaceutics. Some of the applications are listed below. Antiseptics: The antiseptic properties of Essential Oil make them active against wide range of bacteria as on antibiotic resistant strains. In addition to this they are also against fungi and yeasts. The most common sources of essential oils used as antiseptics are: Cinnamon, Thyme, Clover, Eucalyptus, Culin savory, Lavender. Citral, geraniol, linalool and thymol are much more potent than phenol. [1] Expectorants and diuretics: When used externally, essential oils like (Lessence de terebenthine) increase microcirculation and provide a slight local anesthetic action. Till now, essential oils are used in a number of ointments, cream and gels, whereby they are known to be very effective in relieving sprains and other articular pains. Oral administration of essential oils like eucalyptus or pin oils, stimulate ciliated epithelial cells to secrete mucus. On the renal system, these are known to increase vasodilation and in consequence bring about a diuretic effect. Spasmolytic and sedative: Essential oils from the Umbellifereae family, Mentha species and verbena are reputed to decrease or eliminate gastrointestinal spasms. These essential oils increase secretion of gastric juices. In other cases, they are known to be effective against insomnia. METHODS OF EXTRACTION: The following are the methods of extraction of Essential Oil and their drawbacks. 2.4.1 Solvent-Extraction: In the Solvent-Extraction method of Essential Oils recovery, an extracting unit is loaded with perforated trays of essential oil plant material and repeatedly washed with the solvent. A hydrocarbon solvent is used for extraction. All the extractable material from the plant is dissolved in the solvent. This includes highly volatile aroma molecules as well as non-aroma waxes and pigments. The extract is distilled to recover the solvent for future use. The waxy mass that remains is known as the concrete. The concentrated concretes are further processed to remove the waxy materials which dilute the pure essential oil. To prepare the absolute from the concrete, the waxy concrete is warmed and stirred with alcohol (ethanol). During the heating and stirring process the concrete breaks up into minute globules. Since the aroma molecules are more soluble in alcohol than the waxes, an efficient separation of the two results. This is not considered the best method for extraction as the solvents can leave a small amount of residue behind which could cause allergies and effect the immune system. 2.4.2 Maceration: Maceration actually creates more of infused oil rather than an Essential Oil. Plant matter is soaked in vegetable oil, heated and strained at which point it can be used for massage. This method is not desirable because it changes the composition of oil. 2.4.2 Cold Pressing: This method is used to extract the Essential Oils from citrus rinds such as orange, lemon, grapefruit and bergamot. This method involves the simple pressing of the rind at about 120 degrees F to extract the oil. The rinds are separated from the fruit, are ground or chopped and are then pressed. The result is a watery mixture of essential oil and liquid which will separate given time. Little alteration from the oils original state occurs these citrus oils retain their bright, fresh, uplifting aromas like that of smelling a wonderfully ripe fruit. The drawback of this method is, oils extracted using this method have a relatively short shelf life. 2.4.3 Effleurage: This is one of the traditional ways of extracting oil from flowers. The process involves layering fat over the flower petals. After the fat has absorbed the essential oils, alcohol is used to separate and extract the oils from the fat. The alcohol is then evaporated and the Essential Oil is collected. 2.4.4 Super Critical CO2 Extraction: Supercritical CO2 extraction (SCO2) involves carbon dioxide heated to 87 degrees F and pumped through the plant material at around 8,000 psi, under these conditions; the carbon dioxide is likened to a dense fog or vapor. With release of the pressure in either process, the carbon dioxide escapes in its gaseous form, leaving the Essential Oil behind. The usual method of extraction is through steam distillation. After extraction, the properties of a good quality essential oil should be as close as possible to the essence of the original plant. The key to a good essential oil is through low pressure and low temperature processing. High temperatures, rapid processing and the use of solvents alter the molecular structure, will destroy the therapeutic value and alter the fragrance. 2.4.5 Turbo Distillation Extraction: Turbo distillation is suitable for hard-to-extract or coarse plant material, such as bark, roots, and seeds. In this process, the plants soak in water and steam is circulated through this plant and water mixture. Throughout the entire process, the same water is continually recycled through the plant material. This method allows faster extraction of essential oils from hard-to-extract plant materials. Dr.A.Sahoo et al have studied that Steam Distillation is a special type of distillation or a separation process for temperature sensitive materials like oils, resins, hydrocarbons, etc. which are insoluble in water and may decompose at their boiling point. The temperature of the steam must be high enough to vaporize the oil present, yet not so high that it destroys the plants or burns the essential oils. The experiment has been carried out for the extraction of oil from Eucalyptus which has high essential oil content. Such Eucalyptus essential oil, which have been used as perfume and chemical raw materials for a long time, are now been studied as renewable sources of energy. G. Anitescu et al have studied that ripe fruits of Coriander sativum L. were extracted by steam distillation and by supercritical fluid extraction (SFE), using CO2 in a two-stage separation system. An inexpensive thermal expansion procedure for supercritical fluid delivery has been developed. The identification of components was performed by gas chromatography and mass spectrometry (GCà ±MS). The percentage composition of the 40 identified compounds was compared with the composition of commercial coriander oil extracted by hydro distillation. Roy Teranishi et al have studied that system combines steam distillation and liquid-liquid extraction to recover volatiles from fats and oils. Oil is pumped in at the top of a spinning-band distillation column, in which the oil is heated to100 C and spread to a thin film. As the oil film drops down to the pot, steam, which is introduced at the bottom, travels upward to strip the volatiles from the oil. The steam distillate is extracted in a liquid-liquid extractor incorporated in the system, and the extracted water is recycled as steam. Stripped oil in the pot serves as a liquid seal to force steam up the column. The level of the oil in the pot is maintained automatically by an overflow system. Many liters of oil can be pumped through this system to be stripped of volatiles by steam. The volatiles can be isolated easily from the small amount of solvent recycled in the liquid-liquid extractor. Referring to the above literature review, it was found that Steam Distillation method is an appropriate and economical method for extraction of Essential Oil. 2.4.6 Extraction of Essential Oils Using Steam distillation Method: Steam distillation is a special type of distillation or a separation process for temperature sensitive materials like oils, resins, hydrocarbons, etc. which are insoluble in water and may decompose at their boiling point. The fundamental nature of steam distillation is that it enables a compound or mixture of compounds to be distilled at a temperature substantially below that of the boiling point(s) of the individual constituent(s). Essential oils contain substances with boiling points up to 200à °C or higher temperatures. In the presence of steam or boiling water, however, these substances are volatilized at a temperature close to 100à °C, at atmospheric pressure. Fresh, or sometimes dried, botanical material is placed in the plant chamber of the still and the steam is allows to pass through the herb material under pressure which softens the cells and allows the Essential Oil to escape in vapor form. The temperature of the steam must be high enough to vaporize the oil present, yet not so high that it destroys the plants or burns the Essential Oils.à Besides the steam tiny droplets of Essential Oil evaporates and travel through a tube into the stills condensation chamber. Here Essential Oil vapors condense with the steam.à The essential oil forms a film on the surface of the water.à To separate the Essential Oil from the water, the film is then decanted or skimmed off the top.à The remaining water, a byproduct of distillation, is called floral water, distillate, or hydrosol. It retains many of the therapeutic properties of the plant, making it valuable in skin care for facial mists and toners (A solution containing chemicals that can c hange the color of a photographicà print).à In certain situations, floral water may be preferable to be pure essential oil, such as when treating a sensitive individual or a child, or when a more diluted treatment is required. Rose hydrosol, for example, is commonly used for its mild antiseptic and soothing properties, as well as its pleasing floral aroma. A number of factors determine the final quality of a steam distilled essential oil. Apart from the plant material, most important are time, temperature and pressure, and the quality of the distillation equipment. Essential oils are very complex products. Each is made up of many, sometimes hundreds, of distinct molecules which come together to form the oils aroma and therapeutic properties. Some of these molecules are fairly delicate structures which can be altered or destroyed by adverse environmental conditions. So, much like a fine meal is more flavorful when made with patience, most oils benefit from a long, slow cooking process. It is possible that longer distillation times may give more complete oil. It is also possible however, that longer distillation time may lead to the accumulation of more artifacts than normal. This may have a curious effect of appearing to improving the odor, as sometimes when materials that have a larger number of components are sniffed, the perception i s often of slightly increased sophistication, added fullness and character, and possibly, and extra pleasantness. Advantages of using Steam Distillation: The advantage of Steam Distillation is that it is a relatively cheap process to operate at a basic level, and the properties of oils produced by this method are not altered. As steam reduces the boiling point of a particular component of the oil, it never decomposes in this method. This method apart from being economical, it is also relatively faster than other methods. CHAPTER 3:à EXPERIMENTAL WORK 3.1 Experimental Setup: The schematic diagram of experimental setup is shown below. The experiment was conducted in a Clevengers Apparatus. Apparatus consist of one round bottom flask of 1000ml which is connected with another two way round flask which holds raw material. The top flask is connected with condenser through the connecter. The separating funnel is used for the separation of essential oil and water. 3.2 Experimental Procedure: Fresh leaves (rosemary) or bark (cinnamon) are cut into pieces less than 2 X 2 cm within half a day after collection and 150-200 g boiled with 500 ml of distilled water in a Clevenger apparatus until oil distillation ceased after 5-6 h. The volume of essential oils was determined from a calibrated trap. The essential oils in the distillate were dried over anhydrous Na2SO4 and kept in the freezer. 3.3 Analysis of Essential Oils: Analysis of Essential Oil was done using Gas Chromatography with Mass spectrometer to know the composition of oil and to the quantity of each composition. 3.3.1 Gas Chromatography-Mass Spectrometer: Gas Chromatography-Mass Spectrometry (GC-MS) is a method that combines the features of gas-liquid chromatography and mass spectrometry to identify different substances within a test sample. Applications of GC-MS include drug detection, fire investigation, environmental analysis, explosives investigation, and identification of unknown samples. Additionally, it can identify trace elements in materials that were previously thought to have disintegrated beyond identification. [7] Instrumentation: The GC-MS is composed of two major building blocks: the gas chromatograph and the mass spectrometer. The gas chromatograph utilizes a capillary column which depends on the columns dimensions (length, diameter, film thickness) as well as the phase properties (e.g. 5% phenyl polysiloxane). The difference in the chemical properties between different molecules in a mixture will separate the molecules as the sample travels the length of the column. The molecules take different amounts of time (called the retention time) to come out of (elute from) the gas chromatograph, and this allows the mass spectrometer downstream to capture, ionize, accelerate, deflect, and detect the ionized molecules separately. The mass spectrometer does this by breaking each molecule into ionized fragments and detecting these fragments using their mass to charge ratio. These two components, used together, allow a much finer degree of substance identification than either unit used separately. It is not possible to make an accurate identification of a particular molecule by gas chromatography or mass spectrometry alone. The mass spectrometry process normally requires a very pure sample while gas chromatography using a traditional detector (e.g. Flame Ionization Detector) detects multiple molecules that happen to take the same amount of time to travel through the column (i.e. have the same retention time) which results in two or more molecules to co-elute. Sometimes two different molecules can also have a similar pattern of ionized fragments in a mass spectrometer (mass spectrum). Combining the two processes makes it extremely unlikely that two different molecules will behave in the same way in both a gas chromatograph and a mass spectrometer. Therefore when an identifying mass spectrum appears at a characteristic retention time in a GC-MS analysis, it typically lends to increased certainty that the analyte of interest is in the sample. [7] 3.4 Experimental Observation: Experiment had been conducted using different plant materials at different temperatures and time of heating, keeping pressure constant (atmospheric pressure). CHAPTER 4:à RESULTS AND DISCUSSION 4.1 Inferences: Volume of Essential Oil obtained from a particular plant material was different for different temperatures and at a particular temperature for different time of heating. Volume of Essential Oil obtained is less in comparison to hydrosol of the same plant material. Its variation along with temperature and time of heating is shown in graphs drawn below. 4.1.1 Graph showing variation of Volume of Essential Oil against Temperature, obtained from Orange peels. From the graph we can observe that volume of Essential Oil obtained from orange peels is almost increasing linearly with Temperature, if we ignore the slight decline in volume at 900C. The decline may be due to leakage of vapor during Steam Distillation or because of improper decantation. 4.1.2 Graph showing variation of Volume of Essential Oil against Temperature, obtained from Eucalyptus leaves. From the above graph we can observe that volume of Essential Oil obtained is negligible before the components of the oil reach to their boiling
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